Chlorine Dioxide
Chlorine dioxide (ClO2) is a highly effective,
eco-friendly micro biocide that carries US EPA, FDA and UK Government
approvals for many of its uses. Chlorine
dioxide is a selective oxidant that eliminates both planktonic
and sessile bacteria, disinfects surfaces, and rapidly destroys
biofilms.
ClO2 is a stable, dissolved gas that is a strong bactericide and
virucide at concentrations as low as 0.1 ppm. With minimal contact
time, it is highly effective against many pathogenic organisms including
Legionella, Listeria, Salmonella, amoebal cysts, Giardia cysts,
E. Coli, and Cryptosporidium. Importantly, CIO2 also destroys biofilms
so bacterial regrowth is significantly impeded.
CIO2 is highly effective when used to control:
- Legionella.
- Biofilms.
- Salmonella.
- Cryptosporidium.
- Giardia Cysts.
- Coliforms.
- Listeria.
- Shigella.
- Algae.
- Amoebae.
- Taste and odour.
- THM/HMM formation.
- Planktonic and sessile organisms.
CIO2 has long been recognised as a very effective biocide and sterilising
agent for both large and small scale industrial and commercial applications.
It is approved and recommended by the United States Environmental
Protection Agency (US EPA) as an environmentally friendly drinking
water additive to replace chlorine (which is known to form carcinogenic
by-products).
The criteria for disinfection, as defined by the US EPA, are as
follows:
- a 99.9% reduction in giardia lamblia (3 log reduction).
- zero lactose fermenting coliform.
- less than 10 cfu/ml non-lactose fermenting coliforms.
- 99.99% reduction in enteric virus (4 log) concentrations.
CIO2 meets these criteria and is now used extensively across the
US, UK and Europe. In the UK, the Building Services Research and
Information Association (BSRIA) has recommended CIO2 as the best
available technology for the control of legionella in hot and cold
water systems.
CIO2 - highly effective disinfectant
Microbial infection is responsible for thousands of deaths and
many more illnesses across the world each year. Frequent outbreaks
of disease have been linked to food handling and processing (Listeria,
Salmonella, Shigella, and E. Coli), drinking water (Giardia, Cryptosporidium)
and hotels, cruise ships, hospitals and office buildings (Legionella).
The incidence of Legionellosis is frequently misdiagnosed as common
pneumonia. This under-reporting of Legionella has recently come
to light as more and more international health organisations recognise
the need for control plans against this potentially deadly disease.
CIO2 is shown to be an effective disinfectant at residual concentrations
between 0.2 and 0.8 ppm. CIO2 acts to penetrate the cell wall of
microorganisms and disrupts metabolic function. This is more efficient
than other oxidisers that just "burn" the surface of whatever
they come in contact with. This allows for lower effective concentrations
of ClO2 to be used when compared to other oxidiser products.
CIO2, like ozone, is a dissolved gas that penetrates biofilm by
molecular diffusion. However, unlike ozone, CIO2 is stable and soluble,
allowing it to travel to the base of the film where it attacks microorganisms
and destroys the biofilm at its point of attachment. Other oxidisers
react mostly on the surface of the biofilm to form an oxidised layer,
like charring on wood. This precludes further penetration. No other
biocide has proved to control biofilm better than CIO2.
CIO2 - effective over a wide pH range
Because CIO2 is a dissolved gas, it does not ionise to form weak
acids (as chlorine and bromine do) in aqueous solutions. This allows
CIO2 to be effective over a wide pH range. For example, the pH dependent
speciation of chlorine produces hypochlorite ion and hypochlorous
acid (HOCl). Hypochlorite is only 1/30 to 1/200 as effective as
HOCl. CIO2 being a neutral species with rapid disinfection kinetics,
is 100% available for disinfection in hard or soft water.
ClO2 - superior to chlorine and bromine
Chlorine and bromine react rapidly with microbiological species
and chemicals in water. This reactivity is both their strength and
weakness. Rapid reaction with microbiological species means a quick
and effective kill; rapid reaction with chemicals such as scale
and corrosion inhibitors in cooling towers means consumption of
the product for other than microbiological control. Since chemical
reactions are usually the first to take place, only the small residual
of the product remaining after the chemical reaction is completed
is available for microbiological control.
Chlorine and bromine have other limitations in addition to low
residual "killing power". They exhibit poor biofilm control.
They do not retain their biocidal efficiency over wide pH ranges.
They are also relatively unstable. Chlorine has the potential to
damage the environment and create health hazards when it combines
with naturally occurring organic materials such as organic acids
from leaves, to form trihalomethanes (THMs) which are suspected
carcinogens. When chlorine and bromine react with chemicals such
as ammonia, nitrogen, and corrosion and scale inhibitors in cooling
tower water they form objectionable by-products while reducing their
effectivity (HAAs).
Summary
CIO2 is a very safe and potent biocide. It is effective over a
wide pH range in both hard and soft water and does not react with
most other water treatment chemicals. Many of its uses are US and
UK Government approved and highly recommended by many researchers.
SafeOx generators are manufactured to the highest quality standards
and represent one of the safest, most reliable and cost effective
ways of generating CIO2 at the point of use. They are suitable for
a range of applications including, healthcare and hospital facilities,
food and beverage processing, ultrapure water treatment, legionella
control, cooling towers and loops, water hygiene, potable water
treatment, waste-water treatment, residential, commercial and industrial
facilities.
For more information please call us on + (44) 161 877 2334
or e-mail info@safeox.com.
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